FEI Gui-qiang, SHEN Yi-ding, WANG Hai-hua, et al. Effects of modif ied poly ( methacryl ic acid) dispersant concentration on rheologicalbehavior of compound slurry and ceramic strength[J]. Acta Materiae Compositae Sinica, 2006, 23(5): 96-100.
Citation: FEI Gui-qiang, SHEN Yi-ding, WANG Hai-hua, et al. Effects of modif ied poly ( methacryl ic acid) dispersant concentration on rheologicalbehavior of compound slurry and ceramic strength[J]. Acta Materiae Compositae Sinica, 2006, 23(5): 96-100.

Effects of modif ied poly ( methacryl ic acid) dispersant concentration on rheologicalbehavior of compound slurry and ceramic strength

  • Through radical copolymerization , modified waterborne poly methacrylic acid (MPMA) with hydrophilicand hydrophobic group s was prepared by reacting ally poly (ehtenoxy ether) , methacrylic acid and methyl methacrylate. Using MPMA as ceramic dispersant , the effect s of MPMA concent ration on the rheological behavior of Diamond/ Feldspar/ Clay compound slurry and ceramic breaking st rength were studied , and simultaneously the reasonsand dispersive mechanism were analyzed. The result s show that MPMA can improve the slurryps rheological properties and the ceramic st rength. The optimum MPMA concent ration is 0. 57 wt % (based on the absolute dry slurry)with p H ranging from 9 to 10. When adding 0. 57 wt % MPMA , the slurryps negative Zeta potential increases from28. 5 mV to 65. 5 mV , and it s zero shear viscosity decreases from 690. 9 mPa·s to 81. 6 mPa·s. At the same time , it sthixot ropy area reaches the minimum , and the slurry exhibit s Newton flow behavior. Compared with ceramic withinorganic dispersant addition , the ceramic with MPMA addition owns higher breaking st rength , which is increasedfrom 160 MPa to 268 MPa.
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